ISO 9001:2015 Registered • Technical Whitepaper

Wholesale Ultrafine Ammonium Oxalate Manufacturers & Suppliers

Precision-engineered ammonium oxalate monohydrate (NH₄)₂C₂O₄·H₂O with sub-micron and narrow particle size distributions (D50 < 5–25 µm), exceptional chemical purity (≥99.8%), and ultra-low heavy metal thresholds for rare earth purification, metallurgy, electronic ceramics, and specialty synthesis.

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Explore YANXA's specification-led export grades. Every batch is rigorously certified, batch-tracked, and packaged for dangerous goods maritime and air transport.

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≥99.8%
Chemical Assay Purity
<10 µm
Custom D50 Particle Granularity
≤5 ppm
Ultra-Low Heavy Metal Index
100%
Batch Traceability & COA Issued
Executive Material Profile

High-Yield Ultrafine Ammonium Oxalate Engineering

Ammonium oxalate monohydrate (CAS No. 6009-70-7, Molecular Formula: C₂H₈N₂O₄·H₂O) is an essential organic dicarboxylic acid diammonium salt utilized where high selectivity, controllable precipitation kinetics, and residue-free thermal decomposition are non-negotiable. YANXA delivers optimized particle size distributions (PSD), specialized anti-caking morphology, and strict ionic impurity thresholds required by modern industrial automation.

Controlled Micronization

Standard ammonium oxalate crystals often present irregular needle-like geometries susceptible to crushing and heavy caking. Our closed-loop fluid-energy jet milling delivers spherical or pseudo-cubic ultrafine particles with narrow Span indices ((D90-D10)/D50 < 1.2), preventing process agglomeration.

  • Customized D10, D50, D90 grain sizing
  • Sub-micron milling down to D50 2.5 µm
  • Enhanced surface area for instant dissolution kinetics

Trace Cation & Anion Control

For applications in electronic component dielectric formulations and optical-grade rare earth extraction, parasitic ions such as Fe, Pb, Cl, and SO₄ can degrade downstream performance. YANXA implements fractional multi-stage recrystallization to achieve ppm-level impurity caps.

  • Total Fe ≤ 0.0002% (2 ppm)
  • Heavy Metals (as Pb) ≤ 0.0005% (5 ppm)
  • Chloride (Cl⁻) ≤ 0.001%, Sulfate (SO₄²⁻) ≤ 0.002%

Zero-Residue Decomposition

Unlike alkali oxalates (such as sodium or potassium oxalate), ammonium oxalate undergoes clean endothermic sublimation and thermal breakdown above 200°C into gaseous ammonia, carbon dioxide, carbon monoxide, and water vapor, leaving zero ash residue in ceramic or catalyst calcination.

  • Residue after ignition (sulfated ash) ≤ 0.015%
  • Volatile mass release without inorganic contamination
  • Safe matrix pore-former for ceramic monoliths
Analytical Data Verification

Ultrafine Ammonium Oxalate Technical Data Sheet (TDS)

We supply diverse industrial and analytical classifications tailored to specific technical protocols. The parameters below illustrate typical batch values validated by ICP-MS, laser particle diffraction (Mastersizer 3000), and automated potentiometric titration.

Analytical Parameter Electronic & Optical Grade Industrial Rare-Earth Grade Fine Analytical Reagent (AR) Testing Methodology
Assay [(NH₄)₂C₂O₄·H₂O] ≥ 99.85% ≥ 99.0% ≥ 99.5% Redox Titration (KMnO₄)
Median Particle Size (D50) 5.0 – 12.0 µm 15.0 – 35.0 µm 40.0 – 80.0 µm Laser Diffraction (Dry Dispersion)
Span [(D90 - D10) / D50] ≤ 1.15 ≤ 1.45 ≤ 1.80 Calculated PSD Distribution
Insoluble Matter in H₂O ≤ 0.003% ≤ 0.02% ≤ 0.005% Gravimetric Method
Residue on Ignition (Ash) ≤ 0.010% ≤ 0.030% ≤ 0.020% 800°C Muffle Furnace Calcination
Chloride (Cl⁻) ≤ 0.0005% (5 ppm) ≤ 0.003% ≤ 0.001% Turbidimetric Analysis
Sulfate (SO₄²⁻) ≤ 0.001% (10 ppm) ≤ 0.005% ≤ 0.002% Barium Sulfate Turbidimetry
Iron (Fe) ≤ 0.0001% (1 ppm) ≤ 0.001% ≤ 0.0002% ICP-OES / Orthophenanthroline
Heavy Metals (as Pb) ≤ 0.0002% (2 ppm) ≤ 0.001% ≤ 0.0005% Atomic Absorption Spectrophotometry
pH Value (50 g/L Solution, 25°C) 6.0 – 7.0 6.0 – 7.2 6.2 – 7.0 Glass Electrode Potentiometry
Macro Industry Solutions

Engineered for High-Consequence Industrial Operations

Ultrafine ammonium oxalate performs critical chemical tasks across global metallurgy, electronics, precision synthesis, and energy storage supply chains.

Rare Earth Separation & Refining

Ammonium oxalate serves as an elite precipitating agent in the fractional separation of heavy and light rare earth elements (Lanthanum, Cerium, Neodymium, Dysprosium, and Yttrium). Ultrafine particles accelerate complexation kinetics, generating uniform rare earth oxalate crystals that calcine smoothly into ultra-pure rare earth oxides (REO > 99.999%) with optimized specific surface area.

Electronic Ceramics & MLCC Capacitors

In multilayer ceramic capacitors (MLCC), barium titanate (BaTiO₃) dopants, and piezoelectric substrates, sub-micron particle size is paramount. Our ultrafine grade prevents local chemical segregation, ensuring uniform grain boundaries, lowered dielectric loss tangents, and repeatable sintering shrinkage without alkali ion cross-contamination.

CMP Slurries & Wafer Surface Finishing

Used as a complexing and chelating buffer in chemical-mechanical planarization (CMP) polishing formulations for copper interconnects and cobalt barrier layers in semiconductor fabrication. Ultrafine purity avoids micro-scratching on silicon wafers while maintaining stable dissolution selectivity across variable pH regimes.

Heterogeneous Catalyst Precursors

Acts as an organic ligand and structure-directing agent in the synthesis of automotive de-NOx catalysts, hydrotreating zeolites, and petrochemical dehydrogenation catalysts. Its clean volatilization during calcination creates uniform micropores and high active metal dispersion without leaving sulfur or sodium residues.

Precision Analytical Reagents

Standardized laboratory-scale quantitative determination of calcium, lead, cerium, and magnesium ions through gravimetric and redox techniques. High analytical assay stability ensures precise molar reactions in biomedical testing, environmental monitoring, and forensic assays.

Lithium-Ion Battery Hydrometallurgical Recycling

Emerging as an environmentally benign leaching and selective precipitation agent for recovering valuable cobalt, nickel, and manganese from shredded spent cathode black mass. Enables closed-loop transition metal recovery with lower carbon intensity than mineral acid extraction.

Manufacturing Excellence

China Factory 4.0: Supply Chain Resilience & Efficiency Advantages

YANXA leverages an integrated production cluster combining continuous synthesis, intelligent DCS process automation, nitrogen-shielded jet milling, and closed-loop environmental controls to guarantee uninterrupted bulk material delivery to international markets.

01

Continuous Synthesis

Automated reaction crystallization utilizing high-purity synthetic oxalic acid and electronic-grade ammonia water under continuous stoichiometry control.

02

Multi-Stage Centrifuging

High-G closed titanium centrifuges wash mother liquor to remove mother ions, lowering chloride and free acid contents below stringent target values.

03

Fluidized Bed Drying

Low-temperature inert gas fluidized bed drying preserves the precise monohydrate crystalline water balance ((NH₄)₂C₂O₄·H₂O) without thermal decomposition.

04

N₂-Jet Micronization

Supersonic nitrogen fluid-energy jet milling with real-time laser diffraction feedback guarantees pinpoint particle cut-offs down to sub-10 micron sizes.

05

Hermetic Packaging

Automated vacuum-heat-sealed barrier packaging with desiccants and nitrogen purge guarantees 24-month caking-free storage for ocean transit.

Supply Assurance & Upstream Synergy

Our raw material access is backed by long-term strategic off-take contracts with foundational chemical synthesis hubs in China, mitigating upstream shortages of ammonia or oxalic acid feedstocks and safeguarding pricing stability for annualized enterprise contracts.

Real-Time SPC Quality Control

Distributed control systems (DCS) continuously monitor pH, supersaturation curves, crystallization temperature cooling profiles, and agitation shearing rates to eliminate lot-to-lot variances across multi-hundred metric ton production campaigns.

Green Closed-Loop Ecology

Equipped with complete waste mother-liquor crystallization recovery loops and advanced SCR flue-gas ammonia stripping systems, maintaining zero unmitigated chemical discharge in full compliance with Chinese national green chemical park standards.

R&D Innovation Horizon

Technical Roadmap & Future Outlook: Next-Gen Ammonium Oxalate

YANXA's material science laboratory collaborates with institutional partners to pioneer advanced surface modifications, non-caking micro-encapsulations, and specialty grades serving decarbonized high-technology manufacturing.

Surface Anti-Caking Engineering

Developing ultra-trace, vapor-phase organosilane functionalized monolayers and food/pharma compatible nano-silica spacing that inhibit recrystallization bridging in humid trans-equatorial maritime containers without compromising solubility.

Sub-Micron (D50 < 2 µm) Powders

Scaling cryogenic fluid-energy nanogrinding to supply sub-2-micron ammonium oxalate powders for advanced solid-state electrolyte precursor precipitation and fine-grain optical crystal dopants requiring instantaneous stoichiometric reactivity.

Automated In-Line Slurry Blends

Providing custom premixed, stabilized saturated ammonium oxalate aqueous concentrates packaged in cleanroom IBC totes for semiconductor and electronic component clients wishing to avoid powder handling and particulate dispersion in-house.

Scope 3 Carbon Tracking

Integrating verified digital product passports (DPP) detailing product carbon footprints (PCF) from feedstock ammonia synthesis to delivery port, empowering global multinational procurement officers to satisfy ESG and CBAM mandates.

Global Commerce Assurance

Localized Support & International Regulatory Compliance

Purchasing specialty chemical compounds across borders requires rigorous adherence to regional safety legislation, customs documentation, and dangerous goods logistics protocols.

REACH, RoHS & TSCA Compliance

Full support for EU REACH dossiers, pre-registrations, SVHC statements, and RoHS compliance certificates. Our regulatory team coordinates with Only Representatives (OR) in Europe and regional agents in North America, Japan, and South Korea to ensure hassle-free customs clearance.

GHS Safety Documentation

Every shipment is matched with compliant 16-section Safety Data Sheets (SDS) in multiple local languages (English, German, French, Spanish, Japanese, Korean) conforming to UN GHS Revision 9 standards, complete with correct toxicological, first-aid, and disposal data.

Certified Export Packaging

Packaged in UN-certified 25 kg polypropylene woven outer bags with heavy-duty PE inner liners, hermetic fiber drums, or 500 kg / 1,000 kg anti-static super-sacks (Type C / Type D). Fumigated heat-treated ISPM-15 wooden pallets or heavy-duty plastic pallets available on request.

Procurement Framework

Fulfilling Global Tier-1 Chemical Procurement Requirements

Enterprise procurement divisions manage complex vendor matrices. YANXA satisfies key vendor qualification audits across operational risk, financial sustainability, technical consistency, and supply contract guarantees.

Lot-to-Lot Consistency (Cpk > 1.33)

Stringent statistical process control safeguards key indices. Every production run is cross-audited against historical master curves, keeping deviations within tightly defined 3-sigma boundaries.

Pre-Shipment COA & Retention

Every commercial lot ships with its actual batch Certificate of Analysis. Physical retained control samples are sealed under inert gas and archived for a minimum of 36 months to ensure comprehensive traceability.

Third-Party Inspection Ready

SGS, Intertek, or BV pre-shipment sampling and analytical re-verification available at loading port (Shanghai, Qingdao, Ningbo) before cargo release, satisfying international commercial letter of credit (L/C) requirements.

Bilingual Technical Engineering

Chemical and material engineering specialists provide real-time consults on dissolution rates, pH buffering curves, precipitation stoichiometry, and custom particle distributions within 24 business hours.

Procurement Knowledgebase

Frequently Asked Questions: Sourcing Ultrafine Ammonium Oxalate

Comprehensive engineering, regulatory, and purchasing answers for material buyers, chemical process engineers, and supply chain managers.

What is the difference between standard ammonium oxalate and ultrafine ammonium oxalate?
Standard commercial ammonium oxalate typically exhibits coarse, needle-shaped or prismatic crystals ranging from 150 µm to over 500 µm in size. These coarse crystals dissolve slowly, settle non-uniformly in automated dosing slurries, and cause inhomogeneous nucleation when precipitating rare earth oxalates. In contrast, ultrafine ammonium oxalate is jet-milled or micro-crystallized to achieve a median particle diameter (D50) between 5 µm and 25 µm with a tight span distribution. This results in significantly faster dissolution rates, high chemical bioavailability, uniform dispersion in solid blends, and homogenous calcination behavior.
How do you prevent ultrafine ammonium oxalate powder from caking during long ocean voyages?
Ammonium oxalate monohydrate is sensitive to ambient thermal fluctuations and relative humidity shifts that drive microscopic dissolution and re-crystallization bridging at crystal contact points. YANXA mitigates caking via three simultaneous methods: (1) Controlled fluidized-bed drying that maintains stoichiometric crystalline water without freeing surface moisture (free moisture ≤ 0.15%); (2) Hermetic double-layer packaging combining an internal heat-welded heavy-gauge polyethylene barrier liner with desiccant packs, surrounded by multi-ply moisture-proof woven packaging; and (3) Optional application of high-purity, trace functional anti-caking flow aids when approved by the client's application datasheet.
What are the primary dangerous goods shipping classifications for ammonium oxalate?
Ammonium oxalate is classified under international transport regulations (IMDG for maritime, IATA for air freight, and ADR for road transport) as an environmentally hazardous or toxic substance due to its oxalate ion content. It carries UN 2811 (Toxic solid, organic, n.o.s.) or is shipped under non-restricted classification depending on concentration, regional authority interpretations, and packaging size. YANXA provides complete dangerous goods declarations (DGD), certified UN performance-tested packaging, and accurate hazard labeling conforming strictly to IMDG Code Class 6.1 guidelines.
Can YANXA tailor the particle size distribution (PSD) for specialized customer projects?
Yes. Our processing lines include variable-frequency fluid-bed air classifiers and high-speed inert-gas jet mills capable of calibrating particle size parameters precisely to your technical requirements. We can isolate cutoffs such as D50 = 8 ± 2 µm with D98 < 20 µm, or customize broader distributions for solid-state reactions. Every custom specification trial is validated via dry or wet dispersion laser diffraction (Malvern Mastersizer 3000) and accompanied by a comprehensive granulometric distribution curve.
What documentation and quality certificates accompany commercial container shipments?
Every shipment dispatched by YANXA is accompanied by an extensive export dossier: (1) Lot-specific Certificate of Analysis (COA) including assay, trace metals, particle size metrics, and ash residue; (2) 16-section GHS-compliant Safety Data Sheet (SDS); (3) Technical Data Sheet (TDS); (4) Commercial Invoice and Detailed Packing List; (5) Certificate of Origin (Form E, Form A, or RCEP depending on buyer destination); and (6) Packing and Container Inspection Certificate confirming seal numbers and dry cargo conditions.
What is the standard lead time and Minimum Order Quantity (MOQ) for wholesale orders?
Standard industrial catalog grades typically carry an MOQ of 1 metric ton (1,000 kg), while custom-micronized sub-10 µm formulations have an MOQ of 2 to 5 metric tons. Routine warehouse stock grades can be packaged and delivered to major export ports (Shanghai, Qingdao) within 7 to 10 days of purchase order confirmation. Custom milling campaigns typically require 15 to 21 working days for synthesis, precision classification, batch QA release, and container stuffing.
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Request Ultrafine Ammonium Oxalate Specifications & Quotations

Submit your target median particle diameter (D50), chemical purity thresholds, annual procurement volume, and destination port. Our engineering team responds with batch COAs, sample test options, and formal pricing within 24 hours.